Literature DB >> 18802571

The preparation of stable aziridinium ions and their ring-openings.

Yongeun Kim1, Hyun-Joon Ha, Sae Young Yun, Won Koo Lee.   

Abstract

The reaction of enantiomerically pure 2-substituted 1-phenylethyl-aziridine with methyl trifluoromethanesulfonate generated a stable methylaziridinium ion, which was reacted with various external nucleophiles, including nitrile, to yield synthetically valuable and optically pure acyclic amine derivatives in a completely regio- and stereoselective manner.

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Year:  2008        PMID： 18802571     DOI： 10.1039/b809124b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles.

Authors:  Nagendra Nath Yadav; Hyun-Joon Ha
Journal:  J Vis Exp       Date:  2018-08-22       Impact factor: 1.355

2.  H12461. Fluorine as a Regiocontrol Element in the Ring Openings of Bicyclic Aziridiniums.

Authors:  Yu-Hong Lam; Kendall N Houk; Janine Cossy; Domingo Gomez Prado; Anne Cochi
Journal:  Helv Chim Acta       Date:  2012-11-19       Impact factor: 2.164

Review 3.  N-(1-Phenylethyl)aziridine-2-carboxylate esters in the synthesis of biologically relevant compounds.

Authors:  Iwona E Głowacka; Aleksandra Trocha; Andrzej E Wróblewski; Dorota G Piotrowska
Journal:  Beilstein J Org Chem       Date:  2019-07-23       Impact factor: 2.883

Review 4.  Synthetic Applications of Aziridinium Ions.

Authors:  Jala Ranjith; Hyun-Joon Ha
Journal:  Molecules       Date:  2021-03-22       Impact factor: 4.411
  4 in total

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