| Literature DB >> 18802551 |
Meghan A Dureen1, A Lough, Thomas M Gilbert, Douglas W Stephan.
Abstract
Catechol borane reacts with the frustrated Lewis pairs tBu2RP (R = tBu, 2-C6H4(C6H5)) and B(C6F5)3 to give the species [(C6H4O2)BPtBu2R][HB(C6F5)3] that can formally be described as either borenium cation or boryl-phosphonium salts; the nature of these species was probed with DFT calculations.Entities:
Year: 2008 PMID： 18802551 DOI： 10.1039/b808348g
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222