Literature DB >> 18800133

Towards uranium catalysts.

Alexander R Fox1, Suzanne C Bart, Karsten Meyer, Christopher C Cummins.   

Abstract

The forefront of research into the complexes of uranium reveals chemical transformations that challenge and expand our view of this unique element. Certain ligands form multiple bonds to uranium, and small, inert molecules such as nitrogen and carbon dioxide become reactive when in complex with the metal. Such complexes provide clues to the catalytic future of uranium, in which the applications of the element extend far beyond the nuclear industry. Most excitingly, the ability of uranium to use its outermost f electrons for binding ligands might enable the element to catalyse reactions that are impossible with conventional, transition-metal catalysts.

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Year:  2008        PMID: 18800133     DOI: 10.1038/nature07372

Source DB:  PubMed          Journal:  Nature        ISSN: 0028-0836            Impact factor:   49.962


  21 in total

1.  Inorganic chemistry: Cation o' nine tails.

Authors:  Polly L Arnold
Journal:  Nature       Date:  2010-08-05       Impact factor: 49.962

2.  Identification of a uranium-rhodium triple bond in a heterometallic cluster.

Authors:  Genfeng Feng; Mingxing Zhang; Penglong Wang; Shuao Wang; Laurent Maron; Congqing Zhu
Journal:  Proc Natl Acad Sci U S A       Date:  2019-08-19       Impact factor: 11.205

3.  The Uranyl Cation as a Visible-Light Photocatalyst for C(sp(3) )-H Fluorination.

Authors:  Julian G West; T Aaron Bedell; Erik J Sorensen
Journal:  Angew Chem Int Ed Engl       Date:  2016-06-20       Impact factor: 15.336

4.  Spontaneous reduction and C-H borylation of arenes mediated by uranium(III) disproportionation.

Authors:  Polly L Arnold; Stephen M Mansell; Laurent Maron; David McKay
Journal:  Nat Chem       Date:  2012-07-15       Impact factor: 24.427

5.  The role of uranium-arene bonding in H2O reduction catalysis.

Authors:  Dominik P Halter; Frank W Heinemann; Laurent Maron; Karsten Meyer
Journal:  Nat Chem       Date:  2017-12-11       Impact factor: 24.427

6.  Uranyl oxo activation and functionalization by metal cation coordination.

Authors:  Polly L Arnold; Anne-Frédérique Pécharman; Emmalina Hollis; Ahmed Yahia; Laurent Maron; Simon Parsons; Jason B Love
Journal:  Nat Chem       Date:  2010-11-23       Impact factor: 24.427

7.  Uranyl dication mediated photoswitching of a calix[4]pyrrole-based metal coordination cage.

Authors:  Juhoon Lee; James T Brewster; Bo Song; Vincent M Lynch; Inhong Hwang; Xiaopeng Li; Jonathan L Sessler
Journal:  Chem Commun (Camb)       Date:  2018-08-21       Impact factor: 6.222

8.  Complexes featuring a linear [N≡U≡N] core isoelectronic to the uranyl cation.

Authors:  H Lars Deubner; Matthias Müller; Stefan S Rudel; Antti J Karttunen; Florian Kraus
Journal:  Nat Chem       Date:  2020-08-03       Impact factor: 24.427

9.  Isolation and characterization of a uranium(VI)-nitride triple bond.

Authors:  David M King; Floriana Tuna; Eric J L McInnes; Jonathan McMaster; William Lewis; Alexander J Blake; Stephen T Liddle
Journal:  Nat Chem       Date:  2013-05-05       Impact factor: 24.427

10.  Systematic analysis of structural and spectroscopic properties of neptunimine (HN=NpH2) and plutonimine (HN=PuH2).

Authors:  Peng Li; Wenxia Niu; Tao Gao
Journal:  J Mol Model       Date:  2015-11-25       Impact factor: 1.810

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