| Literature DB >> 18798672 |
Dong Eun Kim1, In Su Kim, Virginie Ratovelomanana-Vidal, Jean-Pierre Genêt, Nakcheol Jeong.
Abstract
An efficient asymmetric PKR mediated by Rh(I) catalyst at ambient temperature was developed. The reaction utilizing a Rh(I) catalyst bearing a (R)-3,5-diMeC4H4-BINAP ligand at 18-20 degrees C under a reduced partial pressure of CO (0.1 atm) provided PKR products in high chemical yield as well as high enantioselectivity.Entities:
Year: 2008 PMID： 18798672 DOI： 10.1021/jo801236c
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354