Literature DB >> 18778061

Intra/intermolecular direct allylic alkylation via Pd(II)-catalyzed allylic C-H activation.

Song Lin1, Chun-Xiao Song, Gui-Xin Cai, Wen-Hua Wang, Zhang-Jie Shi.   

Abstract

The first catalytic direct alkylation of allylic C-H bonds via Pd(II)-catalysis is described in the absence of base. Polysubstituted cyclic compounds can also be constructed by the intramolecular direct allylic alkylation.

Entities:  

Year:  2008        PMID： 18778061     DOI： 10.1021/ja803452p

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  29 in total

1.  Allylic functionalization of unactivated olefins with Grignard reagents.

Authors:  Hongli Bao; Liela Bayeh; Uttam K Tambar
Journal:  Angew Chem Int Ed Engl       Date:  2014-01-23       Impact factor: 15.336

2.  Diversification of a β-Lactam Pharmacophore via Allylic C-H Amination: Accelerating Effect of Lewis Acid Co-Catalyst.

Authors:  Xiangbing Ben Qi; Grant T Rice; Manjinder S Lall; Mark S Plummer; M Christina White
Journal:  Tetrahedron       Date:  2010-06-26       Impact factor: 2.457

3.  Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer.

Authors:  Gilbert J Choi; Qilei Zhu; David C Miller; Carol J Gu; Robert R Knowles
Journal:  Nature       Date:  2016-10-12       Impact factor: 49.962

4.  Sequential allylic C-H amination/vinylic C-H arylation: a strategy for unnatural amino acid synthesis from α-olefins.

Authors:  Chao Jiang; Dustin J Covell; Antonia F Stepan; Mark S Plummer; M Christina White
Journal:  Org Lett       Date:  2012-02-24       Impact factor: 6.005

5.  Preparation of allyl and vinyl silanes by the palladium-catalyzed silylation of terminal olefins: a silyl-Heck reaction.

Authors:  Jesse R McAtee; Sara E S Martin; Derek T Ahneman; Keywan A Johnson; Donald A Watson
Journal:  Angew Chem Int Ed Engl       Date:  2012-03-01       Impact factor: 15.336

6.  Redox-Neutral ortho Functionalization of Aryl Boroxines via Palladium/Norbornene Cooperative Catalysis.

Authors:  Renhe Li; Feipeng Liu; Guangbin Dong
Journal:  Chem       Date:  2019-03-07       Impact factor: 22.804

7.  Intramolecular [2 + 2] cycloaddition reactions of alkynyl ether derived ketenes. A convenient synthesis of donor-acceptor cyclobutanes.

Authors:  Vincent Tran; Thomas G Minehan
Journal:  Org Lett       Date:  2011-11-21       Impact factor: 6.005

8.  Synthetic versatility in C-H oxidation: a rapid approach to differentiated diols and pyrans from simple olefins.

Authors:  Paul E Gormisky; M Christina White
Journal:  J Am Chem Soc       Date:  2011-07-27       Impact factor: 15.419

9.  Chemo- and regioselective C(sp³)-H arylation of unactivated allylarenes by deprotonative cross-coupling.

Authors:  Nusrah Hussain; Gustavo Frensch; Jiadi Zhang; Patrick J Walsh
Journal:  Angew Chem Int Ed Engl       Date:  2014-02-26       Impact factor: 15.336

10.  Palladium-catalyzed allylic cross-coupling reactions of primary and secondary homoallylic electrophiles.

Authors:  Benjamin J Stokes; Susanne M Opra; Matthew S Sigman
Journal:  J Am Chem Soc       Date:  2012-07-06       Impact factor: 15.419
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