Literature DB >> 18774807

A terminal borylene ruthenium complex: from B-H activation to reversible hydrogen release.

Gilles Alcaraz1, Ulrike Helmstedt, Eric Clot, Laure Vendier, Sylviane Sabo-Etienne.   

Abstract

Starting from RuHCl(H2)(PCy3)2, a terminal ruthenium mesitylborylene complex was obtained via double B-H bond activation of mesitylborane and concomitant release of dihydrogen, such a process being remarkably reversible.

Entities:  

Year:  2008        PMID： 18774807     DOI： 10.1021/ja805164n

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  5 in total

1.  Reversible Borylene Formation from Ring Opening of Pinacolborane and Other Intermediates Generated from Five-Coordinate Tris-Boryl Complexes: Implications for Catalytic C-H Borylation.

Authors:  Behnaz Ghaffari; Britt A Vanchura; Ghayoor A Chotana; Richard J Staples; Daniel Holmes; Robert E Maleczka; Milton R Smith
Journal:  Organometallics       Date:  2015-08-11       Impact factor: 3.876

2.  Structural snapshots of concerted double E-H bond activation at a transition metal centre.

Authors:  Joseph A B Abdalla; Alexa Caise; Christian P Sindlinger; Rémi Tirfoin; Amber L Thompson; Alison J Edwards; Simon Aldridge
Journal:  Nat Chem       Date:  2017-06-12       Impact factor: 24.427

3.  The partial dehydrogenation of aluminium dihydrides.

Authors:  Thomas N Hooper; Samantha Lau; Wenyi Chen; Ryan K Brown; Martí Garçon; Karen Luong; Nathan S Barrow; Andrew S Tatton; George A Sackman; Christopher Richardson; Andrew J P White; Richard I Cooper; Alison J Edwards; Ian J Casely; Mark R Crimmin
Journal:  Chem Sci       Date:  2019-08-13       Impact factor: 9.825

4.  Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes.

Authors:  Carsten Lenczyk; Dipak Kumar Roy; Jörn Nitsch; Krzysztof Radacki; Florian Rauch; Rian D Dewhurst; F Matthias Bickelhaupt; Todd B Marder; Holger Braunschweig
Journal:  Chemistry       Date:  2019-09-17       Impact factor: 5.236

5.  Cooperative B-H bond activation: dual site borane activation by redox active κ2-N,S-chelated complexes.

Authors:  Mohammad Zafar; Asif Ahmad; Suvam Saha; Rongala Ramalakshmi; Thierry Roisnel; Sundargopal Ghosh
Journal:  Chem Sci       Date:  2022-06-23       Impact factor: 9.969
  5 in total

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