Literature DB >> 18771310

Coupled deswelling of multiresponse microgels.

D Capriles-González1, B Sierra-Martín, A Fernández-Nieves, A Fernández-Barbero.   

Abstract

In this article, we study the response of a thermosensitive and ionic microgel to various external stimuli where coupling between different contributions to the total osmotic pressure is needed to describe the observations. We introduce a new Flory solvency parameter chi ( T, Q, n) with strong dependence on the network charge, Q, and salt concentration, n. The scaling exponent for the salt-induced deswelling of the microgel is the signature of the coupling between the mixing and ionic osmotic pressures.

Entities:  

Year:  2008        PMID: 18771310     DOI: 10.1021/jp8003773

Source DB:  PubMed          Journal:  J Phys Chem B        ISSN: 1520-5207            Impact factor:   2.991


  3 in total

Review 1.  Chemically Responsive Hydrogel Deformation Mechanics: A Review.

Authors:  Eanna Fennell; Jacques M Huyghe
Journal:  Molecules       Date:  2019-09-28       Impact factor: 4.411

2.  Universal conformational properties of polymers in ionic nanogels.

Authors:  Hideki Kobayashi; Roland G Winkler
Journal:  Sci Rep       Date:  2016-02-01       Impact factor: 4.379

3.  Two-step deswelling in the Volume Phase Transition of thermoresponsive microgels.

Authors:  Giovanni Del Monte; Domenico Truzzolillo; Fabrizio Camerin; Andrea Ninarello; Edouard Chauveau; Letizia Tavagnacco; Nicoletta Gnan; Lorenzo Rovigatti; Simona Sennato; Emanuela Zaccarelli
Journal:  Proc Natl Acad Sci U S A       Date:  2021-09-14       Impact factor: 11.205

  3 in total

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