Literature DB >> 18758624

Gas-phase synthesis of the rare-gas carbene cation ArCH2+ using doubly ionised bromomethane as a superelectrophilic reagent.

Daniela Ascenzi1, Paolo Tosi, Jana Roithová, Detlef Schröder.   

Abstract

The bimolecular reaction of mass-selected CH3Br2+/CH2BrH2+ dications with argon leads to the rare-gas carbene cation ArCH2+, which represents an example of a new kind of organo rare-gas compound.

Entities:  

Year:  2008        PMID： 18758624     DOI： 10.1039/b811115d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  1 in total

1.  Rational design of an argon-binding superelectrophilic anion.

Authors:  Martin Mayer; Valentin van Lessen; Markus Rohdenburg; Gao-Lei Hou; Zheng Yang; Rüdiger M Exner; Edoardo Aprà; Vladimir A Azov; Simon Grabowsky; Sotiris S Xantheas; Knut R Asmis; Xue-Bin Wang; Carsten Jenne; Jonas Warneke
Journal:  Proc Natl Acad Sci U S A       Date:  2019-04-05       Impact factor: 11.205
  1 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.