Literature DB >> 18758600

An unprecedented, figure-of-eight, dinuclear iridium(I) dicarbene and new iridium(III) 'pincer' complexes.

Matthieu Raynal1, Catherine S J Cazin, Christophe Vallée, Hélène Olivier-Bourbigou, Pierre Braunstein.   

Abstract

An unusual dinuclear Ir(I) complex bridged by two N-heterocyclic biscarbene ligands, forming a 20-membered, figure-of-eight dimetallacycle, and new CNHCCCNHC pincer complexes of Ir(III) have been obtained directly from the bis(imidazolium) precursors and [Ir(micro-Cl)(cod)]2.

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Year:  2008        PMID: 18758600     DOI: 10.1039/b808806c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Luminescent Iridium(III) Complexes Supported by N-Heterocyclic Carbene-based C^C^C-Pincer Ligands and Aromatic Diimines.

Authors:  Lai-Hon Chung; Hoi-Shing Lo; Sze-Wing Ng; Dik-Lung Ma; Chung-Hang Leung; Chun-Yuen Wong
Journal:  Sci Rep       Date:  2015-10-21       Impact factor: 4.379

2.  Experimental and Theoretical Study of NiII - and PdII -Promoted Double Geminal C(sp3 )-H Bond Activation Providing Facile Access to NHC Pincer Complexes: Isolated Intermediates and Mechanism.

Authors:  Fengkai He; Christophe Gourlaouen; Huan Pang; Pierre Braunstein
Journal:  Chemistry       Date:  2022-06-13       Impact factor: 5.020

  2 in total

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