Literature DB >> 18722433

Synthesis of 1-oxadecalins from anisole promoted by tungsten.

Edward C Lis1, Rebecca J Salomon, Michal Sabat, William H Myers, W Dean Harman.   

Abstract

The complex TpW(NO)(PMe3)(eta(2)-anisole) is combined with acrolein or methyl vinyl ketone and various nucleophiles to generate novel chromen complexes. These complexes may be further elaborated by protonation and nucleophilic addition to generate chroman analogues with increased saturation and stereocenters. Treatment with various oxidants effects the decomplexation of the chromen.

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Year:  2008        PMID： 18722433     DOI： 10.1021/ja803605m

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  3 in total

1.  η 2 Coordination of Electron-Deficient Arenes with Group 6 Dearomatization Agents.

Authors:  Jacob A Smith; Spenser R Simpson; Karl S Westendorff; Justin Weatherford-Pratt; Jeffery T Myers; Justin H Wilde; Diane A Dickie; W Dean Harman
Journal:  Organometallics       Date:  2020-06-25       Impact factor: 3.876

Review 2.  Dearomatization strategies in the synthesis of complex natural products.

Authors:  Stéphane P Roche; John A Porco
Journal:  Angew Chem Int Ed Engl       Date:  2011-04-19       Impact factor: 15.336

3.  Phenyl Sulfones: A Route to a Diverse Family of Trisubstituted Cyclohexenes from Three Independent Nucleophilic Additions.

Authors:  Spenser R Simpson; Paolo Siano; Daniel J Siela; Louis A Diment; Brian C Song; Karl S Westendorff; Megan N Ericson; Kevin D Welch; Diane A Dickie; W Dean Harman
Journal:  J Am Chem Soc       Date:  2022-05-20       Impact factor: 16.383
  3 in total

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