Literature DB >> 18710240

Rhodium-catalyzed asymmetric ring-opening alkynylation of azabenzonorbornadienes.

Takahiro Nishimura1, Eiji Tsurumaki, Takahiro Kawamoto, Xun-Xiang Guo, Tamio Hayashi.   

Abstract

Asymmetric ring-opening alkynylation of meso-azabenzonorbornadienes with (triisopropylsilyl)acetylene giving 2-alkynyl-1-aminodihydronaphthalenes took place in high yields with high enantioselectivity in the presence of a rhodium/(R)-DTBM-segphos catalyst.

Entities:  

Year:  2008        PMID： 18710240     DOI： 10.1021/ol801549t

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Palladium-Catalyzed Dearomative syn-1,4-Carboamination.

Authors:  Mikiko Okumura; Alexander S Shved; David Sarlah
Journal:  J Am Chem Soc       Date:  2017-12-05       Impact factor: 15.419

2.  Iridium-catalyzed asymmetric ring-opening reactions of azabenzonorbornadiene with carboxylic acid nucleophiles.

Authors:  Yuhua Long; Wenling Wang; Dingqiao Yang; Han Jiang; Kaixuan Chen; Yali Fang
Journal:  Mol Divers       Date:  2013-11-27       Impact factor: 2.943

3.  Multi-Pathway Consequent Chemoselectivities of CpRuCl(PPh3 )2 /MeI-Catalysed Norbornadiene Alkyne Cycloadditions.

Authors:  Wei-Hua Mu; De-Cai Fang; Shu-Ya Xia; Rui-Jiao Cheng; Gregory A Chass
Journal:  Chemistry       Date:  2016-09-13       Impact factor: 5.236
  3 in total

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