Literature DB >> 18698783

2-Trimethylsilylcorannulenyl trifluoromethanesulfonate: an efficient precursor for 1,2-didehydrocorannulene.

Andrzej Sygula1, Renata Sygula, Lesya Kobryn.   

Abstract

2-Trimethylsilylcorannulenyl trifluoromethanesulfonate, prepared from bromocorannulene, provides a means for generating of 1,2-didehydrocorannulene (corannulyne) under very mild conditions as demonstrated by the high-yield formation of its adducts with dienes.

Entities:  

Year:  2008        PMID: 18698783     DOI: 10.1021/ol801581z

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Curved π-conjugated corannulene dimer diradicaloids.

Authors:  Qing Wang; Pan Hu; Takayuki Tanaka; Tullimilli Y Gopalakrishna; Tun Seng Herng; Hoa Phan; Wangdong Zeng; Jun Ding; Atsuhiro Osuka; Chunyan Chi; Jay Siegel; Jishan Wu
Journal:  Chem Sci       Date:  2018-05-16       Impact factor: 9.825

  1 in total

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