Literature DB >> 18698440

Can the hexamethylhydrazinium dication [Me(3)N-NMe(3)](2+) be prepared?

Yun Zhang1, Christopher A Reed.   

Abstract

The long sought hexamethylhydrazinium(2+) dication, Me(3)N-NMe(3)(2+), calculationally unstable towards "coulombic explosion" because of formal positive charges on adjacent N atoms, can be synthesized and isolated as a CHB(11)Cl(11)(-) carborane salt.

Entities:  

Year:  2008        PMID： 18698440     DOI： 10.1039/b803304h

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  2 in total

1.  H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.

Authors:  Christopher A Reed
Journal:  Acc Chem Res       Date:  2010-01-19       Impact factor: 22.384

2.  The R3O+···H+ hydrogen bond: toward a tetracoordinate oxadionium(2+) ion.

Authors:  Evgenii S Stoyanov; Gorkem Gunbas; Nema Hafezi; Mark Mascal; Irini V Stoyanova; Fook S Tham; Christopher A Reed
Journal:  J Am Chem Soc       Date:  2011-12-22       Impact factor: 15.419
  2 in total

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