Literature DB >> 18688336

Safe, facile radical-based reduction and hydrosilylation reactions in a microreactor using tris(trimethylsilyl)silane.

Arjan Odedra1, Karolin Geyer, Tomas Gustafsson, Ryan Gilmour, Peter H Seeberger.   

Abstract

A highly efficient system for tris(trimethylsilyl)silane (TTMSS) mediated deoxygenation, dehalogenation and hydrosilylation reactions is described in a microstructured device; this convenient platform enables the scale up of radical-based processes.

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Year:  2008        PMID： 18688336     DOI： 10.1039/b803715a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Continuous flow based catch and release protocol for the synthesis of alpha-ketoesters.

Authors:  Alessandro Palmieri; Steven V Ley; Anastasios Polyzos; Mark Ladlow; Ian R Baxendale
Journal:  Beilstein J Org Chem       Date:  2009-05-20       Impact factor: 2.883

Review 2.  Recent applications of the (TMS)3SiH radical-based reagent.

Authors:  Chryssostomos Chatgilialoglu; Jacques Lalevée
Journal:  Molecules       Date:  2012-01-06       Impact factor: 4.411

3.  Radical carbonylations using a continuous microflow system.

Authors:  Takahide Fukuyama; Md Taifur Rahman; Naoya Kamata; Ilhyong Ryu
Journal:  Beilstein J Org Chem       Date:  2009-07-13       Impact factor: 2.883
  3 in total

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