Literature DB >> 18685780

Enantioselective rhodium-catalysed 1,4-additions of 2-heteroarylzinc donors using Me-DUPHOS.

Jérôme Le Nôtre1, Joseph C Allen, Christopher G Frost.   

Abstract

The enantioselective 1,4-addition of 2-(substituted)thienylzinc and 2-furanylzinc reagents has been achieved (up to 99 : 1 er) using a complex derived from [Rh(C(2)H(4))(2)Cl](2) and Me-DUPHOS.

Entities:  

Year:  2008        PMID: 18685780     DOI: 10.1039/b806098c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Uncatalyzed conjugate addition of organozinc halides to enones in DME: a combined experimental/computational study on the role of the solvent and the reaction mechanism.

Authors:  Gianluca Casotti; Gianluca Ciancaleoni; Filippo Lipparini; Chiara Nieri; Anna Iuliano
Journal:  Chem Sci       Date:  2019-11-11       Impact factor: 9.825

  1 in total

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