Literature DB >> 18685761

Generation of a triplet diradical from a donor-acceptor cross conjugate upon acid-induced electron transfer.

Mats O Sandberg1, Osami Nagao, Zhikun Wu, Michio M Matsushita, Tadashi Sugawara.   

Abstract

Enhancement of the electron acceptor ability of a para-quinodiimine unit by double protonation leads to the proton-induced intramolecular electron transfer from the donor unit to the cross-conjugated acceptor, giving rise to ground state triplet diradical reversibly.

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Year:  2008        PMID: 18685761     DOI: 10.1039/b804999h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

Review 1.  Theory and practice of uncommon molecular electronic configurations.

Authors:  Ganna Gryn'ova; Michelle L Coote; Clemence Corminboeuf
Journal:  Wiley Interdiscip Rev Comput Mol Sci       Date:  2015-10-26
  1 in total

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