| Literature DB >> 18683977 |
Anthoni W van Zijl1, Wiktor Szymanski, Ferrnando López, Adriaan J Minnaard, Ben L Feringa.
Abstract
With a consecutive "asymmetric allylic alkylation (AAA)/cross-metathesis (CM)/conjugate addition (CA)" protocol it is possible to synthesize either stereoisomer of compounds containing a vicinal dialkyl array with excellent stereoselectivity. The versatility of this protocol in natural product synthesis is demonstrated in the preparation of the ant pheromones faranal and lasiol.Entities:
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Year: 2008 PMID： 18683977 DOI： 10.1021/jo8010649
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354