Literature DB >> 18683920

Selenidobis(dithiolene)metal(IV) complexes (metal M = Mo, W) potentially related to the nicotinic acid hydroxylase reaction center: redox aspects in electrochemistry and oxygen atom transfer from Me3NO to M(IV) centers.

Hiroyuki Tano1, Reiko Tajima, Hiroyuki Miyake, Shinobu Itoh, Hideki Sugimoto.   

Abstract

Selenidobis(dithiolene)molybdenum(IV) and -tungsten(IV) complexes were synthesized and characterized by several methods including X-ray crystallographic analysis. The five-coordinate M (V)Se species were accessed by one-electron oxidation of the M (IV)Se complexes. M (VI)Se complexes were suggested to be formed as an intermediate in oxygen atom transfer from Me 3NO to the M (IV)Se centers.

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Year:  2008        PMID： 18683920     DOI： 10.1021/ic8009942

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  3 in total

1.  Influence of the oxygen atom acceptor on the reaction coordinate and mechanism of oxygen atom transfer from the dioxo-Mo(VI) complex, Tp(iPr)MoO(2)(OPh), to tertiary phosphines.

Authors:  Partha Basu; Brian W Kail; Charles G Young
Journal:  Inorg Chem       Date:  2010-06-07       Impact factor: 5.165

2.  Chalcogenidobis(ene-1,2-dithiolate)molybdenum(IV) complexes (chalcogenide E = O, S, Se): probing Mo≡E and ene-1,2-dithiolate substituent effects on geometric and electronic structure.

Authors:  Hideki Sugimoto; Hiroyuki Tano; Koichiro Suyama; Tomoya Kobayashi; Hiroyuki Miyake; Shinobu Itoh; Regina P Mtei; Martin L Kirk
Journal:  Dalton Trans       Date:  2010-12-16       Impact factor: 4.390

3.  Partial synthetic models of FeMoco with sulfide and carbyne ligands: Effect of interstitial atom in nitrogenase active site.

Authors:  Linh N V Le; Gwendolyn A Bailey; Anna G Scott; Theodor Agapie
Journal:  Proc Natl Acad Sci U S A       Date:  2021-12-07       Impact factor: 12.779
  3 in total

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