Literature DB >> 18671341

Synthesis and structure of a ferrocenylboron dication.

Holger Braunschweig1, Martin Kaupp, Christoph Lambert, Dörte Nowak, Krzysztof Radacki, Sandra Schinzel, Katharina Uttinger.   

Abstract

Treatment of the borane Br 2BFc (Fc = ferrocenyl) with the Lewis base 4-methylpyridine and Na[BAr (f) 4] [Ar (f) = 3,5-(CF 3) 2C 6H 3] afforded the boron dication [FcB(NC 5H 4-4-Me) 3][BAr (f) 4] 2. This compound is a rare example of a structurally characterized boron dication.

Entities:  

Year:  2008        PMID: 18671341     DOI: 10.1021/ic800876p

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  2 in total

1.  A boron-boron coupling reaction between two ethyl cation analogues.

Authors:  Sebastian Litters; Elisabeth Kaifer; Markus Enders; Hans-Jörg Himmel
Journal:  Nat Chem       Date:  2013-10-13       Impact factor: 24.427

2.  Reactive p-block cations stabilized by weakly coordinating anions.

Authors:  Tobias A Engesser; Martin R Lichtenthaler; Mario Schleep; Ingo Krossing
Journal:  Chem Soc Rev       Date:  2015-11-27       Impact factor: 54.564

  2 in total

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