| Literature DB >> 18665649 |
Kiran Kumar Solingapuram Sai1, Pierre M Esteves, Eduardo Tanoue da Penha, Douglas A Klumpp.
Abstract
The superacid-promoted reactions of alpha-hydroxy and alpha-ketoamides have been studied. Ionization of these compounds leads to varied aryl-substituted oxyindole products. In some cases, electrocyclization can lead to substituted fluorene products. Dicationic, superelectrophilic intermediates are proposed as intermediates leading to the products from alpha-hydroxy and alpha-ketoamides.Entities:
Mesh：
Substances：
Year: 2008 PMID： 18665649 DOI： 10.1021/jo801208m
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354