| Literature DB >> 18662005 |
Jeffrey M Carney1, Patrick J Donoghue, William M Wuest, Olaf Wiest, Paul Helquist.
Abstract
Intramolecular hydroamination of several aminoalkynes catalyzed by silver-phenanthroline complexes is reported. This catalyst system complements previous protocols by employing air- and moisture-stable complexes without compromising activity or reaction control. Some of the hydroamination products are subject to a useful aerobic oxidation. Silver-phenanthroline complexes have successfully demonstrated efficacy in the desymmetrization of a prochiral diyne.Entities:
Mesh：
Substances：
Year: 2008 PMID： 18662005 DOI： 10.1021/ol801458g
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005