| Literature DB >> 18651747 |
Xiao-Liang Tang1, Xiao-Hong Peng, Wei Dou, Jie Mao, Jiang-Rong Zheng, Wen-Wu Qin, Wei-Sheng Liu, Jin Chang, Xiao-Jun Yao.
Abstract
A new 8-hydroxyquinoline-based chemosensor possessing a semirigid structure was designed, and its fluorescent sensing behavior toward metalions was investigated. A prominent fluorescence enhancement only for Cd(2+) was found in aqueous methanol solution. The results clearly suggest that the specific semirigid structure could selectively accommodate Cd(2+) according to ionic radius, which would effectively suppress the intramolecular radiationless transitions from the n pi* state to enhance the fluorescence response.Entities:
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Year: 2008 PMID: 18651747 DOI: 10.1021/ol801382f
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005