| Literature DB >> 18651732 |
Douglas B Grotjahn1, Elijah J Kragulj, Constantinos D Zeinalipour-Yazdi, Valentín Miranda-Soto, Daniel A Lev, Andrew L Cooksy.
Abstract
The secondary structure of a bifunctional catalyst positions a crucial reactive proton in the final intermediate of anti-Markovnikov alkyne hydration to give an aldehyde. NMR coupling and isotopic labeling studies elucidate the location of this proton and its involvement in hydrogen bonding.Entities:
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Year: 2008 PMID： 18651732 DOI： 10.1021/ja803106z
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419