Literature DB >> 18610982

Understanding the behavior of N-tosyl and N-2-pyridylsulfonyl imines in CuII-catalyzed aza-Friedel-Crafts reactions.

Inés Alonso1, Jorge Esquivias, Ramón Gómez-Arrayás, Juan C Carretero.   

Abstract

The different behavior of N-tosyl imines and N-(2-pyridyl)sulfonyl imines in Cu (II)-catalyzed AFCR is described. DFT theoretical calculations on the mode of coordination of the copper atom to both types of substrates allow understanding this different reactivity.

Entities:  

Year:  2008        PMID: 18610982     DOI: 10.1021/jo800986g

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  3 in total

1.  Silver-catalyzed direct benzylation of acetanilide: a highly efficient approach to unsymmetrical triarylmethanes.

Authors:  Yuting Li; Yan Zhu; Guangliang Tu; Jingyu Zhang; Yingsheng Zhao
Journal:  RSC Adv       Date:  2018-08-28       Impact factor: 4.036

2.  Bond cleavage, fragment modification and reassembly in enantioselective three-component reactions.

Authors:  Dan Zhang; Jun Zhou; Fei Xia; Zhenghui Kang; Wenhao Hu
Journal:  Nat Commun       Date:  2015-01-14       Impact factor: 14.919

3.  Nickel-Catalyzed Arylation of Heteroaryl-containing Diarylmethanes: Exceptional Reactivity of the Ni(NIXANTPHOS)-based Catalyst.

Authors:  Xinyu Cao; Sheng-Chun Sha; Minyan Li; Byeong-Seon Kim; Catherine Morgan; Rudan Huang; Xiaodong Yang; Patrick J Walsh
Journal:  Chem Sci       Date:  2015-10-26       Impact factor: 9.825

  3 in total

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