Literature DB >> 18594738

Room-temperature activation of aryl chlorides in Suzuki-Miyaura coupling using a [Pd(micro-Cl)Cl(NHC)]2 complex (NHC = N-heterocyclic carbene).

Olivier Diebolt1, Pierre Braunstein, Steven P Nolan, Catherine S J Cazin.   

Abstract

A straightforwardly synthesised complex, [Pd(micro-Cl)Cl(NHC)](2) (NHC = bis(2,6-diisopropylphenyl)imidazol-2-ylidene, IPr), has been employed to mediate Suzuki-Miyaura reactions involving aryl chlorides at very low catalyst loadings and at room temperature.

Entities:  

Year:  2008        PMID： 18594738     DOI： 10.1039/b804695f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Organotrifluoroborates and monocoordinated palladium complexes as catalysts--a perfect combination for Suzuki-Miyaura coupling.

Authors:  Gary A Molander; Belgin Canturk
Journal:  Angew Chem Int Ed Engl       Date:  2009       Impact factor: 15.336

2.  Suzuki-Miyaura reactions catalyzed by C₂-symmetric Pd-multi-dentate N-heterocyclic carbene complexes.

Authors:  Lan Jiang; Fengjun Shan; Zhengning Li; Defeng Zhao
Journal:  Molecules       Date:  2012-10-16       Impact factor: 4.411
  2 in total

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