Literature DB >> 18594724

Concerted attack of frustrated Lewis acid-base pairs on olefinic double bonds: a theoretical study.

András Stirling1, Andrea Hamza, Tibor András Rokob, Imre Pápai.   

Abstract

A computational approach reveals cooperative action of the preorganized acidic and basic centers of the frustrated P(t-Bu)(3)/B(C(6)F(5))(3) Lewis pair on olefinic bonds as the key to the observed regioselective addition reaction.

Year:  2008        PMID: 18594724     DOI: 10.1039/b804662j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Contrasting Frustrated Lewis Pair Reactivity with Selenium- and Boron-Based Lewis Acids.

Authors:  Lewis C Wilkins; Benjamin A R Günther; Melanie Walther; James R Lawson; Thomas Wirth; Rebecca L Melen
Journal:  Angew Chem Int Ed Engl       Date:  2016-08-03       Impact factor: 15.336

  1 in total

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