| Literature DB >> 18576599 |
Michael W Cooke1, Marie-Pierre Santoni, Garry S Hanan, Frédérique Loiseau, Anna Proust, Bernold Hasenknopf.
Abstract
A synthetic route to linear pairs of Rh2 "paddlewheel" dimers bridged by Ru(II) complexes is presented. A bis(4'-(4-carboxyphenyl)-terpyridine)Ru(II) complex spans two Rh2 dimers and displays a 26 A separation between the dimers. Increased electronic interaction is found for the dimer of dimers without the phenyl groups using bis(4'-(4-carboxy)-terpyridine)Ru(II) as the bridging complex.Entities:
Year: 2008 PMID： 18576599 DOI： 10.1021/ic8003678
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165