Literature DB >> 18572923

Copper(I)-promoted synthesis of chloromethyl ketones from trichloromethyl carbinols.

Ram N Ram1, T P Manoj.   

Abstract

Reaction of several trichloromethyl carbinols with 2 equiv of CuCl/bpy in refluxing DCE for 3 h afforded chloromethyl ketones in excellent yield by 1,2-H shift in the copper-chlorocarbenoid intermediate.

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Year:  2008        PMID： 18572923     DOI： 10.1021/jo8007644

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  3 in total

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Journal:  Molecules       Date:  2022-06-02       Impact factor: 4.927

2.  (Z)-2,3-Di-chloro-1,4-bis-(4-chloro-phen-yl)but-2-ene-1,4-dione.

Authors:  Ram K Tittal; Satish Kumar; R N Ram
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2014-07-11

3.  Brønsted acidic ionic liquid accelerated halogenation of organic compounds with N-Halosuccinimides (NXS).

Authors:  Dejan Vražič; Marjan Jereb; Kenneth K Laali; Stojan Stavber
Journal:  Molecules       Date:  2012-12-21       Impact factor: 4.411
  3 in total

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