| Literature DB >> 18570378 |
Masaki Miyamoto1, Yasuyuki Harada, Mamoru Tobisu, Naoto Chatani.
Abstract
The reaction of 2-(chloromethyl)phenylboronic acid (1) with alkynes in the presence of a Rh(I) complex gave indene derivatives in high yields. The regioselectivity depends on the steric nature of the substituent on the alkynes. A bulky group favors the alpha-position of indenes.Entities:
Year: 2008 PMID： 18570378 DOI： 10.1021/ol8006887
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005