Literature DB >> 18529011

Negishi cross-couplings of unsaturated halides bearing relatively acidic hydrogen atoms with organozinc reagents.

Georg Manolikakes1, Matthias A Schade, Carmen Muñoz Hernandez, Herbert Mayr, Paul Knochel.   

Abstract

A wide range of polyfunctional aryl, heteroaryl, alkyl, and benzylic zinc reagents were coupled with unsaturated halides bearing an acidic NH or OH function, using Pd(OAc)(2) (1 mol %) and S-Phos (2 mol %) as catalyst without the need of protecting groups.

Entities:  

Year:  2008        PMID： 18529011     DOI： 10.1021/ol8009013

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  14 in total

1.  "Designer"-Surfactant-Enabled Cross-Couplings in Water at Room Temperature.

Authors:  Bruce H Lipshutz; Subir Ghorai
Journal:  Aldrichimica Acta       Date:  2012-01-01       Impact factor: 3.667

Review 2.  Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using alkyl-organometallics as reaction partners.

Authors:  Ranjan Jana; Tejas P Pathak; Matthew S Sigman
Journal:  Chem Rev       Date:  2011-02-14       Impact factor: 60.622

3.  Suzuki-Miyaura cross-coupling of unprotected, nitrogen-rich heterocycles: substrate scope and mechanistic investigation.

Authors:  M Alexander Düfert; Kelvin L Billingsley; Stephen L Buchwald
Journal:  J Am Chem Soc       Date:  2013-08-16       Impact factor: 15.419

4.  Dual C-F, C-H Functionalization via Photocatalysis: Access to Multifluorinated Biaryls.

Authors:  Sameera Senaweera; Jimmie D Weaver
Journal:  J Am Chem Soc       Date:  2016-02-18       Impact factor: 15.419

5.  Negishi coupling of secondary alkylzinc halides with aryl bromides and chlorides.

Authors:  Chong Han; Stephen L Buchwald
Journal:  J Am Chem Soc       Date:  2009-06-10       Impact factor: 15.419

6.  Transitioning organic synthesis from organic solvents to water. What's your E Factor?

Authors:  Bruce H Lipshutz; Subir Ghorai
Journal:  Green Chem       Date:  2014-08-01       Impact factor: 10.182

7.  Catalysis in the Service of Green Chemistry: Nobel Prize-Winning Palladium-Catalysed Cross-Couplings, Run in Water at Room Temperature: Heck, Suzuki-Miyaura and Negishi reactions carried out in the absence of organic solvents, enabled by micellar catalysis.

Authors:  Bruce H Lipshutz; Benjamin R Taft; Alexander R Abela; Subir Ghorai; Arkady Krasovskiy; Christophe Duplais
Journal:  Platin Met Rev       Date:  2012-04

8.  Mild and general conditions for negishi cross-coupling enabled by the use of palladacycle precatalysts.

Authors:  Yang Yang; Nathan J Oldenhuis; Stephen L Buchwald
Journal:  Angew Chem Int Ed Engl       Date:  2012-11-22       Impact factor: 15.336

9.  Reevaluating the Substrate Specificity of the L-Type Amino Acid Transporter (LAT1).

Authors:  Huan-Chieh Chien; Claire Colas; Karissa Finke; Seth Springer; Laura Stoner; Arik A Zur; Brooklynn Venteicher; Jerome Campbell; Colton Hall; Andrew Flint; Evan Augustyn; Christopher Hernandez; Nathan Heeren; Logan Hansen; Abby Anthony; Justine Bauer; Dimitrios Fotiadis; Avner Schlessinger; Kathleen M Giacomini; Allen A Thomas
Journal:  J Med Chem       Date:  2018-08-10       Impact factor: 7.446

10.  Site-Selective C-H alkylation of Complex Arenes by a Two-Step Aryl Thianthrenation-Reductive Alkylation Sequence.

Authors:  Beatrice Lansbergen; Paola Granatino; Tobias Ritter
Journal:  J Am Chem Soc       Date:  2021-05-24       Impact factor: 15.419
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