Pathways of maximum likelihood for rare events in nonequilibrium systems: application to nucleation in the presence of shear.

Even in nonequilibrium systems, the mechanism of rare reactive events caused by small random noise is predictable because they occur with high probability via their maximum likelihood path (MLP). Here a geometric characterization of the MLP is given as the curve minimizing a certain functional under suitable constraints. A general purpose algorithm is also proposed to compute the MLP. This algorithm is applied to predict the pathway of transition in a bistable stochastic reaction-diffusion equation in the presence of a shear flow, and to analyze how the shear intensity influences the mechanism and rate of the transition.