| Literature DB >> 18517212 |
Mariolino Carta1, Kadhum J Msayib, Peter M Budd, Neil B McKeown.
Abstract
The synthesis of novel spirobisindane-based monomers for the preparation of polymers of intrinsic microporosity (PIMs) with bulky, rigid substituents is described. Polymers derived from monomers containing spiro-linked fluorene substituents display enhanced solubility and microporosity due to additional frustration of packing in the solid state.Entities:
Year: 2008 PMID: 18517212 DOI: 10.1021/ol800573m
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005