Literature DB >> 18505288

A domino annulation reaction under Willgerodt-Kindler conditions.

Daniel Kadzimirsz1, Daniel Kramer, Lertnarong Sripanom, Iris M Oppel, Pawel Rodziewicz, Nikos L Doltsinis, Gerald Dyker.   

Abstract

Butanone side chains at arenes and hetarenes, efficiently introduced by a Heck-type reaction, are transformed to annulated thieno[3,2-b]thiophenes in a domino redox process under Willgerodt-Kindler conditions. A nucleophilic aromatic substitution with an intermediary thioenolate is a reasonable key step of this process.

Entities:  

Year:  2008        PMID: 18505288     DOI: 10.1021/jo8005705

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  1 in total

1.  Crystal structure of (4-chloro-phen-yl)[2-(10-hy-droxy-phenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone.

Authors:  L U Sajitha; M Sithambaresan; Jomon P Jacob; M R Prathapachandra Kurup
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2014-10-18
  1 in total

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