| Literature DB >> 18481866 |
Hao He1, Bao-Jian Pei, Ho-Hsuan Chou, Tian Tian, Wing-Hong Chan, Albert W M Lee.
Abstract
Cyclic sulfonyl hydrazine was demonstrated for the first time as a new functionality for organocatalysis. A series of six-membered cyclic hydrazines derived from camphor sulfonic acid were synthesized. With trichloroacetic acid as cocatalyst, they are efficient organocatalysts for enantioselective Diels-Alder reactions with good chemical yields and up to 96% ee. The reactions took place in brine at 0 degrees C to room temperature.Entities:
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Year: 2008 PMID： 18481866 DOI： 10.1021/ol8005826
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005