| Literature DB >> 18480909 |
Naoki Hayashi1, Yusuke Hirokawa, Ikuya Shibata, Makoto Yasuda, Akio Baba.
Abstract
Hydroindation of allenes and radical cyclization of 1,2,7-trienes (allenenes) were accomplished by HInCl2 with high regioselectivity to afford a variety of cyclic compounds. The resulting vinylic indiums could be used for successive coupling reactions in a one-pot procedure. The use of HInCl2 generated slowly in situ is extremely effective for the radical cyclization.Entities:
Year: 2008 PMID： 18480909 DOI： 10.1039/b803314e
Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876