Literature DB >> 18461944

Rare-earth metal alkyl and hydride complexes stabilized by a cyclen-derived [NNNN] macrocyclic ancillary ligand.

Masato Ohashi1, Marcin Konkol, Iker Del Rosal, Romuald Poteau, Laurent Maron, Jun Okuda.   

Abstract

A trinuclear rare-earth metal hydride complex was synthesized from the dialkyl complex supported by a monoanionic [NNNN] macrocycle and shown to catalyze the hydrosilylation of olefins efficiently.

Entities:  

Year:  2008        PMID: 18461944     DOI: 10.1021/ja801771u

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  2 in total

1.  Molecular heterometallic hydride clusters composed of rare-earth and d-transition metals.

Authors:  Takanori Shima; Yi Luo; Timothy Stewart; Robert Bau; Garry J McIntyre; Sax A Mason; Zhaomin Hou
Journal:  Nat Chem       Date:  2011-09-18       Impact factor: 24.427

2.  Novel polymerization catalysts and hydride clusters from rare-earth metal dialkyls.

Authors:  Masayoshi Nishiura; Zhaomin Hou
Journal:  Nat Chem       Date:  2010-03-24       Impact factor: 24.427

  2 in total

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