| Literature DB >> 18447412 |
William P Krekelberg1, Vincent K Shen, Jeffrey R Errington, Thomas M Truskett.
Abstract
The residual multiparticle entropy (RMPE) of two- and three-dimensional fluids changes sign near the freezing line, providing a quasiuniversal "one-phase" rule for the location of the liquid-solid transition. We present new simulation results for d-dimensional hard-sphere fluids (d=1-5) which show, however, that this freezing criterion fails in other spatial dimensions. The results also call into question the idea that a change in sign of the RMPE implies the emergence of a new kind of local structural order in the fluid.Year: 2008 PMID: 18447412 PMCID: PMC2671177 DOI: 10.1063/1.2916697
Source DB: PubMed Journal: J Chem Phys ISSN: 0021-9606 Impact factor: 3.488