Literature DB >> 18442231

A new family of spin-crossover complexes based on a FeII(tetrazolyl)4(MeCN)2-type core.

Agata Białońska1, Robert Bronisz, Marek Weselski.   

Abstract

A bitopic ligand 2-hydroxy-1-(tetrazol-1-yl)-3-(tetrazol-2-yl)propane (12pbtzOH) was synthesized and reacted with Fe(ClO4)(2).6H2O, giving a 1D coordination polymer {[Fe(12pbtzOH)2(CH3CN)2](ClO4)(2).2CH3CN} infinity that exhibits a high-spin to low-spin transition (T1/2(downward arrow)=T1/2(upward arrow) congruent with 104 K). This is an unprecedented example of an iron(II) complex containing Fe(tetrazolyl) 4(MeCN)2 cores.

Entities:  

Year:  2008        PMID： 18442231     DOI： 10.1021/ic8002993

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  4 in total

1.  (1R,2R)-1,2-Diphenyl-1,2-bis-(1H-tetra-zol-1-yl)ethane.

Authors:  Franz Werner; Kurt Mereiter; Kenji Tokuno; Yuki Inagaki; Miki Hasegawa
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-10-13

2.  Poly[[bis-{μ(3)-tris-[2-(1H-tetra-zol-1-yl)eth-yl]amine}copper(II)] bis-(perchlorate)].

Authors:  Franz Werner; Kenji Tokuno; Miki Hasegawa; Wolfgang Linert; Kurt Mereiter
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-03-13

3.  A Modified Synthetic Pathway for the Synthesis of so far Inaccessible N1-Functionalized Tetrazole Ligands - Synthesis and Characterization of the 1D Chain-Type Spin Crossover Compound [Fe(3ditz)3](BF4)2.

Authors:  Danny Müller; Christian Knoll; Berthold Stöger; Werner Artner; Michael Reissner; Peter Weinberger
Journal:  Eur J Inorg Chem       Date:  2013-01-17       Impact factor: 2.524

4.  Spin state switching in iron coordination compounds.

Authors:  Philipp Gütlich; Ana B Gaspar; Yann Garcia
Journal:  Beilstein J Org Chem       Date:  2013-02-15       Impact factor: 2.883
  4 in total

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