Literature DB >> 18440586

Separation and fluorine nuclear magnetic resonance spectroscopic (19F NMR) analysis of individual branched isomers present in technical perfluorooctanesulfonic acid (PFOS).

Gilles Arsenault1, Brock Chittim, Jun Gu, Alan McAlees, Robert McCrindle, Valerie Robertson.   

Abstract

The production of perfluoroalkylsulfonate (PFOS) derivatives from linear alkyl precursors using electrochemical fluorination is not a clean process but, instead, gives complex mixtures. This study reports the isolation and (19)F NMR characterization of eleven perfluorooctanesulfonate isomers from a commercial mixture. This allowed the quantification of the individual CF(3) branched isomers that predominate in technical PFOS.

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Year:  2008        PMID: 18440586     DOI: 10.1016/j.chemosphere.2007.06.096

Source DB:  PubMed          Journal:  Chemosphere        ISSN: 0045-6535            Impact factor:   7.086


  3 in total

1.  Dominant entropic binding of perfluoroalkyl substances (PFASs) to albumin protein revealed by 19F NMR.

Authors:  Michael Fedorenko; Jessica Alesio; Anatoliy Fedorenko; Angela Slitt; Geoffrey D Bothun
Journal:  Chemosphere       Date:  2020-09-02       Impact factor: 7.086

2.  Mechanochemical mineralization of "very persistent" fluorocarbon surfactants ‒ 6:2 fluorotelomer sulfonate (6:2FTS) as an example.

Authors:  Mengnan Lu; Giovanni Cagnetta; Kunlun Zhang; Jun Huang; Gang Yu
Journal:  Sci Rep       Date:  2017-12-07       Impact factor: 4.379

3.  Analysis of Specific Perfluorohexane Sulfonate Isomers by Liquid Chromatography-Tandem Mass Spectrometry: Method Development and Application in Source Apportionment.

Authors:  Liping Yang; Xin Chen; Lingyan Zhu; Yixin Wang; Guoqiang Shan
Journal:  J Anal Methods Chem       Date:  2022-09-22       Impact factor: 2.594

  3 in total

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