Literature DB >> 18433172

Novel chiral calix[4]arenes by direct asymmetric epoxidation reaction.

Carlo Bonini1, Lucia Chiummiento, Maria Funicello, Maria Teresa Lopardo, Paolo Lupattelli, Alessandro Laurita, Andrea Cornia.   

Abstract

We report the first asymmetric synthesis of trans optically active (+) C 2 1,3-bisarylepoxide of calix[4]arene in excellent chemical yield and >99% ee, and its enantiospecific conversion to the corresponding bis-dioxolane.

Entities:  

Year:  2008        PMID: 18433172     DOI: 10.1021/jo800301m

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  1 in total

1.  Inherently chiral calixarenes: synthesis, optical resolution, chiral recognition and asymmetric catalysis.

Authors:  Shao-Yong Li; Yao-Wei Xu; Jun-Min Liu; Cheng-Yong Su
Journal:  Int J Mol Sci       Date:  2011-01-17       Impact factor: 5.923

  1 in total

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