Literature DB >> 18417339

Experimental and kinetic modelling studies on the acid-catalysed hydrolysis of the water hyacinth plant to levulinic acid.

B Girisuta1, B Danon, R Manurung, L P B M Janssen, H J Heeres.   

Abstract

A comprehensive experimental and modelling study on the acid-catalysed hydrolysis of the water hyacinth plant (Eichhornia crassipes) to optimise the yield of levulinic acid (LA) is reported (T=150-175 degrees CH2SO4 = 0.1-1M, water hyacinth intake=1-5wt%). At high acid concentrations (>0.5M), LA was the major organic acid whereas at low acid concentrations (<0.1M) and high initial intakes of water hyacinth, the formation of propionic acid instead of LA was favoured. The highest yield of LA was 53mol% (35wt%) based on the amount of C6-sugars in the water hyacinth (T=175 degrees CH2SO4 =1M , water hyacinth intake=1wt%). The LA yield as a function of the process conditions was modelled using a kinetic model originally developed for the acid-catalysed hydrolysis of cellulose and good agreement between the experimental and modelled data was obtained.

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Year:  2008        PMID: 18417339     DOI: 10.1016/j.biortech.2008.02.045

Source DB:  PubMed          Journal:  Bioresour Technol        ISSN: 0960-8524            Impact factor:   9.642


  8 in total

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Authors:  Jenny N M Tan-Soetedjo; Henk H van de Bovenkamp; Ria M Abdilla; Carolus B Rasrendra; Jacob van Ginkel; Hero J Heeres
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4.  Catalytic conversion of cellulose to levulinic acid by metal chlorides.

Authors:  Lincai Peng; Lu Lin; Junhua Zhang; Junping Zhuang; Beixiao Zhang; Yan Gong
Journal:  Molecules       Date:  2010-08-02       Impact factor: 4.411

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6.  Auto-Crosslinked Rigid Foams Derived from Biorefinery Byproducts.

Authors:  Pierluigi Tosi; Gerard P M van Klink; Alain Celzard; Vanessa Fierro; Luc Vincent; Ed de Jong; Alice Mija
Journal:  ChemSusChem       Date:  2018-07-25       Impact factor: 8.928

7.  Identification and characterization of levulinyl-CoA synthetase from Pseudomonas citronellolis, which differs phylogenetically from LvaE of Pseudomonas putida.

Authors:  Hiroshi Habe; Hideaki Koike; Yuya Sato; Yosuke Iimura; Tomoyuki Hori; Manabu Kanno; Nobutada Kimura; Kohtaro Kirimura
Journal:  AMB Express       Date:  2019-08-13       Impact factor: 3.298

8.  Production of 5-hydroxymethylfurfural from Japanese cedar (Cryptomeria japonica) in an ionic liquid, 1-methylimidazolium hydrogen sulfate.

Authors:  Ryoya Ito; Hisashi Miyafuji
Journal:  Sci Rep       Date:  2021-11-23       Impact factor: 4.379

  8 in total

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