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Literature DB >> 18412386

Room-temperature Kumada cross-coupling of unactivated aryl chlorides catalyzed by N-heterocylic carbene-based nickel(II) complexes.

Abstract

The Kumada cross-coupling reaction of a variety of unactivated aryl chlorides, vinyl chlorides, and heteroaryl chlorides catalyzed by nickel(II) complexes containing pyridine-functionalized NHC ligands is described. The catalysts are so active that the reactions proceed at room temperature in excellent yields.

Entities: Chemical

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Year: 2008 PMID： 18412386 DOI： 10.1021/jo800197u

Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354

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Cited

6 in total

Review 1. Nickel-catalyzed cross-couplings involving carbon-oxygen bonds.

Authors: Brad M Rosen; Kyle W Quasdorf; Daniella A Wilson; Na Zhang; Ana-Maria Resmerita; Neil K Garg; Virgil Percec
Journal: Chem Rev Date: 2010-12-06 Impact factor: 60.622

2. N-Heterocyclic Carbene Bound Nickel(I) Complexes and Their Roles in Catalysis.

Authors: Kainan Zhang; Martin Conda-Sheridan; Shayna Cooke; Janis Louie
Journal: Organometallics Date: 2011-05-09 Impact factor: 3.876

3. Carbon-carbon cross-coupling reactions catalyzed by a two-coordinate nickel(II)-bis(amido) complex via observable Ni(I) , Ni(II) , and Ni(III) intermediates.

Authors: Michael I Lipschutz; T Don Tilley
Journal: Angew Chem Int Ed Engl Date: 2014-05-30 Impact factor: 15.336

Room-temperature Kumada cross-coupling of unactivated aryl chlorides catalyzed by N-heterocylic carbene-based nickel(II) complexes.

Review 1. Nickel-catalyzed cross-couplings involving carbon-oxygen bonds.

2. N-Heterocyclic Carbene Bound Nickel(I) Complexes and Their Roles in Catalysis.

3. Carbon-carbon cross-coupling reactions catalyzed by a two-coordinate nickel(II)-bis(amido) complex via observable Ni(I) , Ni(II) , and Ni(III) intermediates.

Review 4. Halogenating Enzymes for Active Agent Synthesis: First Steps Are Done and Many Have to Follow.

Review 5. Pd-Catalyzed Cross-Couplings: On the Importance of the Catalyst Quantity Descriptors, mol % and ppm.

6. Triorganoindium Reagents in Rh-Catalyzed C⁻H Activation/C⁻C Cross-Coupling Reactions of 2-Arylpyridines.