| Literature DB >> 18412344 |
Ning Shangguan1, Warren J Hehre, William S Ohlinger, Mary Pat Beavers, Madeleine M Joullié.
Abstract
The first total synthesis of roquefortine C is achieved by implementation of a novel elimination strategy to construct the thermodynamically unstable E-dehydrohistidine moiety. Molecular modeling studies are presented which explain the instability of the roquefortine C structure compared to that of isoroquefortine C.Entities:
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Year: 2008 PMID： 18412344 DOI： 10.1021/ja800067q
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419