Literature DB >> 18399405

Spontaneous resolution of a 3D chiral polyoxometalate-based polythreaded framework consisting of an achiral ligand.

Ya-Qian Lan1, Shun-Li Li, Zhong-Min Su, Kui-Zhan Shao, Jian-Fang Ma, Xin-Long Wang, En-Bo Wang.   

Abstract

Two enantiomerically 3D chiral POM-based architectures have been constructed based on the achiral ligand bbi, [V10O26](4-) polyoxoanion and mixed valence Cu(I/II) without a chiral auxiliary, and they represent the first examples of enantiomerically 3D POM-based compounds using achiral ligands.

Entities:  

Year:  2008        PMID: 18399405     DOI: 10.1039/b714413j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Three novel polyoxometalate-based inorganic-organic hybrid materials based on 2,6-bis(1,2,4-triazol-1-yl)pyridine.

Authors:  Yingying Wu; Xuefei Li; Ying Liu; Ge Xiao; Yijiao Huang; Yamin Li; Dongbin Dang; Yan Bai
Journal:  RSC Adv       Date:  2019-04-16       Impact factor: 4.036

  1 in total

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