Literature DB >> 18389111

Highly active and stereoselective zirconium and hafnium alkoxide initiators for solvent-free ring-opening polymerization of rac-lactide.

Amanda J Chmura1, Matthew G Davidson, Catherine J Frankis, Matthew D Jones, Matthew D Lunn.   

Abstract

Under solvent-free conditions (at 130 degrees C), zirconium and hafnium amine tris(phenolate) alkoxides are extremely active, well-controlled, single-site initiators for the ring-opening polymerization of rac-lactide, yielding highly heterotactic polylactide.

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Year:  2008        PMID： 18389111     DOI： 10.1039/b718678a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  1 in total

1.  Monomeric Ti(IV) homopiperazine complexes and their exploitation for the ring opening polymerisation of rac-lactide.

Authors:  Stuart L Hancock; Mary F Mahon; Matthew D Jones
Journal:  Chem Cent J       Date:  2013-08-06       Impact factor: 4.215
  1 in total

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