Literature DB >> 18385854

Synthesis of mono- and 1,3-disubstituted allenes from propargylic amines via palladium-catalysed hydride-transfer reaction.

Hiroyuki Nakamura1, Makoto Ishikura, Tsuyuka Sugiishi, Takaya Kamakura, Jean-François Biellmann.   

Abstract

Mono- and 1,3-disubstituted allenes were synthesized from the corresponding propargylamines via palladium-catalysed hydride-transfer reaction. In the current transformation, propargylic amines can be handled as allenyl anion equivalents and introduced into various electrophiles to be transformed into allenes under palladium-catalyzed conditions.

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Year:  2008        PMID： 18385854     DOI： 10.1039/b718298h

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  2 in total

1.  Scope of the palladium-catalyzed aryl borylation utilizing bis-boronic acid.

Authors:  Gary A Molander; Sarah L J Trice; Steven M Kennedy; Spencer D Dreher; Matthew T Tudge
Journal:  J Am Chem Soc       Date:  2012-07-06       Impact factor: 15.419

2.  On the Origin of the Promoting Effect Exerted by Magnesium in the ZnCl2-Catalyzed Synthesis of N,N-Diisopropylethylamine.

Authors:  Zeng Hong; Jiancheng Ruan; Xinzhi Chen; Chao Qian; Xin Ge; Shaodong Zhou
Journal:  ACS Omega       Date:  2020-11-11
  2 in total

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