Literature DB >> 18374378

Mechanistic insights and new products of the reaction of steroid sapogenins with NaNO2 and BF3.Et2O in acetic acid.

Yliana López1, Karen M Ruíz-Pérez, Rebeca Yépez, Rosa Santillan, Marcos Flores-Alamo, Martín A Iglesias-Arteaga.   

Abstract

A detailed analysis of the course of the reaction of steroid sapogenins with NaNO(2) and BF(3).Et(2)O in acetic acid is presented and some evidences on the involved mechanism are provided. Two new products of the studied reaction were isolated and unambiguously characterized with the aid of NMR and single crystal X-ray diffraction.

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Year:  2008        PMID: 18374378     DOI: 10.1016/j.steroids.2008.02.003

Source DB:  PubMed          Journal:  Steroids        ISSN: 0039-128X            Impact factor:   2.668


  1 in total

1.  A Convenient Synthesis of (16S,20S)-3β-hydroxy-5α-pregnane-20,16-carbolactam and its N-alkyl Derivatives.

Authors:  Agnieszka Wojtkielewicz; Damian Pawelski; Przemysław Bazydło; Aneta Baj; Stanisław Witkowski; Jacek W Morzycki
Journal:  Molecules       Date:  2020-05-20       Impact factor: 4.411

  1 in total

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