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Literature DB >> 18368170

Lewis acid-catalyzed hydrogenation: B(C6F5)3-mediated reduction of imines and nitriles with H2.

Preston A Chase¹, Titel Jurca, Douglas W Stephan.

Abstract

The Lewis acid B(C(6)F(5))(3) has been found to be an efficient catalyst for the direct hydrogenation of imines and the reductive ring-opening of aziridines with H(2) under mild conditions; addition of a bulky phosphine allows for the reduction of protected nitriles.

Entities: Chemical

Year: 2008 PMID： 18368170 DOI： 10.1039/b718598g

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

14 in total

1. A dual site catalyst for mild, selective nitrile reduction.

Authors: Zhiyao Lu; Travis J Williams
Journal: Chem Commun (Camb) Date: 2014-01-09 Impact factor: 6.222

2. Attempted synthesis of ortho-phenylene phosphino-tritylium cations.

Authors: Kantapat Chansaenpak; Mengxi Yang; François P Gabbaï
Journal: Philos Trans A Math Phys Eng Sci Date: 2017-08-28 Impact factor: 4.226

3. Design and reactions of a carbon Lewis base/boron Lewis acid frustrated Lewis pair.

Authors: Jennifer Möricke; Birgit Wibbeling; Constantin G Daniliuc; Gerald Kehr; Gerhard Erker
Journal: Philos Trans A Math Phys Eng Sci Date: 2017-08-28 Impact factor: 4.226

4. Direct observation of a borane-silane complex involved in frustrated Lewis-pair-mediated hydrosilylations.

Authors: Adrian Y Houghton; Juha Hurmalainen; Akseli Mansikkamäki; Warren E Piers; Heikki M Tuononen
Journal: Nat Chem Date: 2014-09-28 Impact factor: 24.427

5. A combined "electrochemical-frustrated lewis pair" approach to hydrogen activation: surface catalytic effects at platinum electrodes.

Authors: Elliot J Lawrence; Robin J Blagg; David L Hughes; Andrew E Ashley; Gregory G Wildgoose
Journal: Chemistry Date: 2014-11-07 Impact factor: 5.236

Lewis acid-catalyzed hydrogenation: B(C6F5)3-mediated reduction of imines and nitriles with H2.

1. A dual site catalyst for mild, selective nitrile reduction.

2. Attempted synthesis of ortho-phenylene phosphino-tritylium cations.

3. Design and reactions of a carbon Lewis base/boron Lewis acid frustrated Lewis pair.

4. Direct observation of a borane-silane complex involved in frustrated Lewis-pair-mediated hydrosilylations.

5. A combined "electrochemical-frustrated lewis pair" approach to hydrogen activation: surface catalytic effects at platinum electrodes.

6. Metal-free hydrogenation catalyzed by an air-stable borane: use of solvent as a frustrated Lewis base.

7. Versatile Catalytic Hydrogenation Using A Simple Tin(IV) Lewis Acid.

8. Hydrogen activation using a novel tribenzyltin Lewis acid.

9. An electrochemical study of frustrated Lewis pairs: a metal-free route to hydrogen oxidation.

10. Heterolytic Splitting of Molecular Hydrogen by Frustrated and Classical Lewis Pairs: A Unified Reactivity Concept.