Literature DB >> 18368163

The first side-on bound metal complex of diazene, HN[double bond]NH.

Leslie D Field1, Hsiu L Li, Scott J Dalgarno, Peter Turner.   

Abstract

The side-on bound metal complex of diazene cis-[Fe(NH[double bond]NH)(dmpe)(2)] was synthesised by reaction of [Fe(dmpe)(2)Cl(2)] with hydrazine in the presence of potassium graphite and characterised by (15)N NMR spectroscopy and X-ray crystallography.

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Year:  2008        PMID： 18368163     DOI： 10.1039/b802039f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  10 in total

Review 1.  Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes.

Authors:  Matthew J Chalkley; Marcus W Drover; Jonas C Peters
Journal:  Chem Rev       Date:  2020-04-30       Impact factor: 60.622

2.  A five-coordinate phosphino/acetate iron(II) scaffold that binds N2, N2H2, N2H4, and NH3 in the sixth site.

Authors:  Caroline T Saouma; Curtis E Moore; Arnold L Rheingold; Jonas C Peters
Journal:  Inorg Chem       Date:  2011-10-17       Impact factor: 5.165

3.  Dinitrogen complexes of sulfur-ligated iron.

Authors:  Ayumi Takaoka; Neal P Mankad; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2011-05-16       Impact factor: 15.419

4.  Transformation of an [Fe(η2-N2H3)]+ species to π-delocalized [Fe2(μ-N2H2)](2+/+) complexes.

Authors:  Caroline T Saouma; R Adam Kinney; Brian M Hoffman; Jonas C Peters
Journal:  Angew Chem Int Ed Engl       Date:  2011-03-10       Impact factor: 15.336

5.  Conversion of Fe-NH2 to Fe-N2 with release of NH3.

Authors:  John S Anderson; Marc-Etienne Moret; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2013-01-08       Impact factor: 15.419

6.  Triggering N(2) uptake via redox-induced expulsion of coordinated NH(3) and N(2) silylation at trigonal bipyramidal iron.

Authors:  Yunho Lee; Neal P Mankad; Jonas C Peters
Journal:  Nat Chem       Date:  2010-05-16       Impact factor: 24.427

7.  An Fe-N₂ Complex That Generates Hydrazine and Ammonia via Fe═NNH₂: Demonstrating a Hybrid Distal-to-Alternating Pathway for N₂ Reduction.

Authors:  Jonathan Rittle; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2016-03-21       Impact factor: 15.419

8.  A Synthetic Single-Site Fe Nitrogenase: High Turnover, Freeze-Quench (57)Fe Mössbauer Data, and a Hydride Resting State.

Authors:  Trevor J Del Castillo; Niklas B Thompson; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2016-04-15       Impact factor: 15.419

9.  Mononuclear five- and six-coordinate iron hydrazido and hydrazine species.

Authors:  Caroline T Saouma; Connie C Lu; Jonas C Peters
Journal:  Inorg Chem       Date:  2012-09-05       Impact factor: 5.165

10.  Ammonia formation by a thiolate-bridged diiron amide complex as a nitrogenase mimic.

Authors:  Yang Li; Ying Li; Baomin Wang; Yi Luo; Dawei Yang; Peng Tong; Jinfeng Zhao; Lun Luo; Yuhan Zhou; Si Chen; Fang Cheng; Jingping Qu
Journal:  Nat Chem       Date:  2013-03-17       Impact factor: 24.427
  10 in total

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