Shape of the particulate beam attenuation spectrum and its inversion to obtain the shape of the particulate size distribution.

The link between the spectral shape of the beam attenuation spectrum and the shape of the particle size distribution (PSD) of oceanic particles is revisited to evaluate the extent to which one can be predicted from the other. Assuming a hyperbolic (power-law) PSD, N(D) ? D(-xi), past studies have found for an infinite distribution of nonabsorbing spheres with a constant index of refraction that the attenuation spectrum is hyperbolic and that the attenuation spectral slope gamma is related to the PSD slope xi by xi = gamma + 3. Here we add a correction to this model because of the finite size of the biggest particle in the population. This inversion model is given by xi = gamma + 3 - 0.5 exp(-6gamma). In most oceanic observations xi > 3, and the deviation between these two models is negligible. To test the robustness of this inversion, we perturbed its assumptions by allowing for populations of particles that are nonspherical, or absorbing, or with an index of refraction that changes with wavelength. We found the model to provide a good fit for the range of parameters most often encountered in the ocean. In addition, we found that the particulate attenuation spectrum, c(p)(lambda), is well described by a hyperbolic relation to the wavelength c(p) ? lambda(-gamma) throughout the range of the investigated parameters, even when the inversion model does not apply. This implies that knowledge of the particulate attenuation at two visible wavelengths could provide, to a high degree of accuracy, the particulate attenuation at other wavelengths in the visible spectrum.